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Arsenic

Element 33 · 74.922 u

Metalloid p-block Period 4 Group 15 Solid at RT Wikipedia →

Arsenic is a notorious metalloid historically known as the 'king of poisons'.

Physical Properties

Atomic Mass74.922 u
Density5.776 g/cm³
Melting Point1090.0 K
Boiling Point887.0 K
AppearanceMetallic gray
State at Room TempSolid

Chemical Properties

Electronegativity2.18 (Pauling)
1st Ionization Energy947.0 kJ/mol
Electron Affinity78.2 kJ/mol
Oxidation States-3, +2, +3, +5

Atomic Properties

Electron Configuration[Ar] 3d10 4s2 4p3
Atomic Radius114.0 pm
Covalent Radius119.0 pm
Van der Waals Radius185.0 pm

Discovery

Discovered ByAlbertus Magnus
Discovery Year1250
LocationGermany
Named AfterGreek 'arsenikon' meaning yellow orpiment

About Arsenic

Arsenic occurs in many minerals and as a steel-gray, brittle solid. It sublimes rather than melting at standard pressure. Despite its toxicity, arsenic trioxide treats acute promyelocytic leukemia.

Uses & Applications

Semiconductors (gallium arsenide), wood preservatives, pesticides, lead alloys, and cancer treatment.

Fun Fact

Arsenic was the 'king of poisons' and 'poison of kings' -- a favored murder weapon in the Middle Ages because it was undetectable.

Isotopes

Mass Number Abundance Half-Life Stable
75 1.0% - Yes

Electron Configuration

[Ar] 3d10 4s2 4p3

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